Title :
IR luminescence from subvalent bismuth in phosphate glass and glass-ceramic matrices: A new insight into the nature of luminescent Bi species
Author :
Romanov, A. ; Fattakhova, Z. ; Zhigunov, D. ; Buchnev, L. ; Korchak, V. ; Sulimov, V.
Author_Institution :
Res. Comput. Center, Moscow State Univ., Moscow, Russia
Abstract :
To elucidate the role of different subvalent forms of bismuth in observed NIR luminescence we have prepared the phosphate glasses with compositions: 0.8 KMe(PO3)3, 0.2 KBi(PO3)4, where Me = Mg, Ca, Zn. Glasses were fabricated from NH4H2PO4, Bi2O3, ZnO, MgO and CaCO3 starting materials by melting at 1000 οC in air.
Keywords :
bismuth; luminescence; optical glass; phosphate glasses; Bi2O3; CaCO3; IR luminescence; KBi(PO3)4; KCa(PO3)3; KMg(PO3)3; KZn(PO3)3; MgO; NH4H2PO4; ZnO; glass ceramic matrices; phosphate glass; subvalent bismuth; temperature 1000 degC; Board of Directors; Glass;
Conference_Titel :
Lasers and Electro-Optics Europe (CLEO EUROPE/EQEC), 2011 Conference on and 12th European Quantum Electronics Conference
Conference_Location :
Munich
Print_ISBN :
978-1-4577-0533-5
Electronic_ISBN :
Pending
DOI :
10.1109/CLEOE.2011.5942831