Modeling of carbon nanotube Schottky barrier reduction for holes in air

A model is proposed for the previously reported lower Schottky barrier for holes Φ_Bh in air than in vacuum at a metallic electrode-semiconducting carbon nanotube (CNT) junction. We consider that there is a transition region between the electrode and the CNT, and an appreciable potential can drop there. The role of the oxidation is to increase this potential drop with negatively charged oxygen molecules on the CNT, leading to lower Φ_Bh after oxidation. The mechanism prevails in both p- and n-CNTs, and the model consistently explains the key experimental findings.