Title :
Optimisation of simulation of diffusional transport to microsphere electrode and its application to electrogenerated chemiluminescence
Author :
Svir, I.B. ; Oleinick, A.I. ; Compton, R.G.
Author_Institution :
Kharkiv State Tech. Univ. of Radio Electron., Ukraine
Abstract :
We show the application of the three layer finite implicit (3LFI) method for finding a solution of the ECL diffusion microsphere problem during bipolar impulse non-stationary electrolysis. Two different transformed coordinates in the radial coordinate were employed, a conformal map and an exponentially expanding grid, with aim of optimising the modelling of the diffusion under non steady state conditions
Keywords :
chemiluminescence; diffusion; electrolysis; optimisation; ECL diffusion microsphere problem; bipolar impulse non-stationary electrolysis; diffusional transport; electrogenerated chemiluminescence; exponentially expanding grid; microsphere electrode; non steady state conditions; optimisation; radial coordinate; simulation; three layer finite implicit method; transformed coordinates; Boundary conditions; Chemistry; Electrochemical processes; Electrodes; Equations; Kinetic theory; Laboratories; Microelectrodes; Steady-state; Voltage;
Conference_Titel :
Laser and Fiber-Optical Networks Modeling, 2000. Proceedings of LFNM 2000. 2nd International Workshop on
Conference_Location :
Kharkiv
Print_ISBN :
0-7803-6380-9
DOI :
10.1109/LFNM.2000.854057
