Optimisation of simulation of diffusional transport to microsphere electrode and its application to electrogenerated chemiluminescence

Author

Svir, I.B. ; Oleinick, A.I. ; Compton, R.G.

Author_Institution

Kharkiv State Tech. Univ. of Radio Electron., Ukraine

fYear

2000

fDate

2000

Firstpage

118

Lastpage

121

Abstract

We show the application of the three layer finite implicit (3LFI) method for finding a solution of the ECL diffusion microsphere problem during bipolar impulse non-stationary electrolysis. Two different transformed coordinates in the radial coordinate were employed, a conformal map and an exponentially expanding grid, with aim of optimising the modelling of the diffusion under non steady state conditions

Keywords

chemiluminescence; diffusion; electrolysis; optimisation; ECL diffusion microsphere problem; bipolar impulse non-stationary electrolysis; diffusional transport; electrogenerated chemiluminescence; exponentially expanding grid; microsphere electrode; non steady state conditions; optimisation; radial coordinate; simulation; three layer finite implicit method; transformed coordinates; Boundary conditions; Chemistry; Electrochemical processes; Electrodes; Equations; Kinetic theory; Laboratories; Microelectrodes; Steady-state; Voltage;

fLanguage

English

Publisher

ieee

Conference_Titel

Laser and Fiber-Optical Networks Modeling, 2000. Proceedings of LFNM 2000. 2nd International Workshop on

Conference_Location

Kharkiv

Print_ISBN

0-7803-6380-9

Type

conf

DOI

10.1109/LFNM.2000.854057

Filename

854057