Title :
Delta-Doping Effects on Quantum-Dot Solar Cells
Author :
Polly, Stephen J. ; Forbes, David V. ; Driscoll, K. ; Hellstrom, Staffan ; Hubbard, Seth M.
Author_Institution :
Rochester Inst. of Technol., Rochester, NY, USA
Abstract :
The effects of delta-doping InAs quantum-dot (QD)-enhanced GaAs solar cells were studied both through modeling and device experimentation. Delta doping of two, four, and eight electrons per QD, as well as nine holes per QD, was used in this study. It was observed that QD doping reduced Shockley-Read-Hallrecombination in the QDs, which results in a reduced dark current and an improved open-circuit voltage over undoped QD devices. A voltage recovery of 121 mV was observed for the eight-electron sample compared with the undoped sample. QD doping had no positive effects on subbandgap photon collection but actually degraded bulk and QD response as doping levels were increased by limiting minority carrier collection through the QD region. Despite this, an absolute AM0 efficiency improvement of 1.41% was observed for the four-electron sample over the undoped QD device while maintaining a current enhancement.
Keywords :
III-V semiconductors; dark conductivity; doping profiles; electron-hole recombination; gallium arsenide; indium compounds; minority carriers; semiconductor quantum dots; solar cells; GaAs-InAs; InAs quantum-dot-enhanced GaAs solar cell; Shockley-Read-Hall recombination; absolute AM0 efficiency improvement; current enhancement; dark current; delta-doping effects; doping levels; minority carrier collection; open-circuit voltage; subbandgap photon collection; voltage recovery; Doping; Gallium arsenide; Photonic band gap; Photovoltaic cells; Radiative recombination; Semiconductor process modeling; Silicon; InAs; delta doping; quantum dot (QD);
Journal_Title :
Photovoltaics, IEEE Journal of
DOI :
10.1109/JPHOTOV.2014.2316677