Title :
High performance hydrogen selective membranes prepared using rapid processing method
Author :
Gopalakrishnan, Suraj ; Nair, Balagopal N. ; Nakao, Shin-ichi
Author_Institution :
ARC Centre for Functional Nanomaterials, Queensland Univ., Brisbane, Qld.
Abstract :
The production of hydrogen using membrane based reforming technology is one important application where the membrane is required to withstand high temperatures and pressures to achieve maximum efficiency from an equilibrium-limited reaction. Microporous silica membranes offer a viable alternative to polymer and metal composite membranes. The processing of silica membranes including sol-gel and chemical vapor deposition (CVD) methods are discussed adequately in the literature. The sol-gel method allows for the precise control of pore structure while CVD results in chemically homogenous deposits inside the porous substrates to yield better selectivity. The main problem associated with these methods is the long processing times to prepare these membranes, resulting in increased cost of production for the processing of large batches. Here the paper reports an advance in membrane processing that could drastically reduce membrane processing time without compromising performance.
Keywords :
chemical vapour deposition; hydrogen; membranes; polymers; porous semiconductors; silicon compounds; sol-gel processing; SiO2; chemical vapor deposition; equilibrium-limited reaction; hybrid processing; hydrogen selective membranes; metal composite membranes; microporous silica membranes; polymer; rapid processing method; reforming technology; sol-gel; Biomembranes; Chemical industry; Chemical vapor deposition; Fuel cells; Hydrogen; Inductors; Production; Silicon compounds; Temperature; Thermodynamics;
Conference_Titel :
Nanoscience and Nanotechnology, 2006. ICONN '06. International Conference on
Conference_Location :
Brisbane, Qld.
Print_ISBN :
1-4244-0452-5
Electronic_ISBN :
1-4244-0452-5
DOI :
10.1109/ICONN.2006.340665