Title :
Hydrophobic Modification and Characterization of Calcium Carbonate Nanopowders
Author_Institution :
Hunan Chem. Vocational Technol. Coll., Zhuzhou, China
Abstract :
Calcium carbonate nanopowder is an important engineering material used for various painting and polymer-based composite additive and filler. The hydrophobic modification on surface of calcium carbonate nanopowder was performed by using three silane coupling agents: i.e. 3-Aminopropyl triethoxysilane (APTES), 3-mercapto-propyl triethoxysilane (MPTES) and 3-ATRP trimethoxysilane (KH570). The Fourier Transform Infrared Spectrometry (FT-IR) was used to confirm the surface chemical coupling variations. The contact angle meter was used to determine its hydrophobic property. After KH570 modification, the sample of nanopowder showed the best hydrophobic property with a contact angle of 107°. The findings are of significance to enhance nano-calcium carbonate dispersibility and compatibility in organic media.
Keywords :
Fourier transform spectra; calcium compounds; chemical engineering; contact angle; hydrophobicity; infrared spectra; nanoparticles; organic compounds; surface treatment; 3-ATRP trimethoxysilane; 3-Aminopropyl triethoxysilane; 3-mercapto-propyl triethoxysilane; Fourier transform infrared spectrometry; KH570 modification; calcium carbonate nanopowder; contact angle meter; engineering material; hydrophobic modification; hydrophobic property; nanocalcium carbonate compatibility; nanocalcium carbonate dispersibility; organic media; painting; polymer based composite additive; polymer based composite filler; silane coupling agent; surface chemical coupling variations; hydrophobic property; nano-calcium carbonate; silane coupling agent; surface modification;
Conference_Titel :
Digital Manufacturing and Automation (ICDMA), 2010 International Conference on
Conference_Location :
ChangSha
Print_ISBN :
978-0-7695-4286-7
DOI :
10.1109/ICDMA.2010.51