Optical limiting and photochemical properties of some azaporphyrine complexes under powerful laser excitation

Author

Kuznetsova, R.T. ; Nechaeva, J.V. ; Mayer, G.V. ; Ivanova, S.S. ; Stuzhin, P.A.

Author_Institution

Siberian Phys.-Tech. Inst., Tomsk State Univ.

Volume

2

fYear

2003

fDate

16-20 Sept. 2003

Firstpage

195

Abstract

The aim of this study is the investigation of the optical limiting behavior of some azaporphyrins and related RSA mechanism, since all mechanisms have additive character. The optical limiting by RSA mechanisms depends on the structure of the coordination center in azaporphyrin complexes, solvent, initial transparency, energy of photon and intensity of radiation. Complexes octaphenyltetraazaporphyrine with the group III metals bearing halides as axial ligands, were chosen as objects in this study

Keywords

laser beam effects; optical limiters; optical saturable absorption; organic compounds; photochemistry; RSA mechanism; axial ligands; azaporphyrine complexes optical limiting; coordination center; laser radiation intensity; octaphenyltetraazaporphyrine; photochemical properties; photon energy; powerful laser excitation; Absorption; Chemical lasers; Laser excitation; Laser theory; Optical refraction; Optical saturation; Photochemistry; Power lasers; Solvents; Stimulated emission;

fLanguage

English

Publisher

ieee

Conference_Titel

Advanced Optoelectronics and Lasers, 2003. Proceedings of CAOL 2003. First International Conference on

Conference_Location

Alushta, Crimea

Print_ISBN

0-7803-7948-9

Type

conf

DOI

10.1109/CAOL.2003.1251310

Filename

1251310