Title :
A study of electrochemical and microchemical processes in the fluorocarbon-lithium model coin cells BR2325 under storage and their influence for the long life of "CF1+x-Li” sources
Author :
Mitkin, Valentin N. ; Galkin, Peter S. ; Denisova, Tatjana N. ; Koreneva, Ol´ga V. ; Shinelev, Eugene A. ; Alexandrov, Alexander B. ; Moukhin, Viktor V.
Author_Institution :
Inst. of Inorg. Chem., Acad. of Sci., Novosibirsk, Russia
Abstract :
The main reason for corrosion phenomena in CF1+x-Li cells in the presence of cathodic composites of the unremoved moisture even at a level of 0.0N mass. % is the generation small amounts of HF. Here, the authors study the electrochemical and microstructural processes in such batteries. These phenomena decrease the storage life of CF1+x-Li cells and accelerate the self-discharge processes
Keywords :
carbon compounds; cathodes; cells (electric); electrochemical electrodes; electrochemistry; lithium; BR2325 coin cells; Li-CF; Li-CF1+x batteries; cathodic composites; corrosion phenomena; electrochemical processes; microchemical processes; moisture; self-discharge processes; storage life; Assembly; Chemicals; Chemistry; Corrosion; Hafnium; Infrared spectra; Inorganic materials; Lithium; Material storage; Moisture;
Conference_Titel :
Battery Conference on Applications and Advances, 1998., The Thirteenth Annual
Conference_Location :
Long Beach, CA
Print_ISBN :
0-7803-4098-1
DOI :
10.1109/BCAA.1998.653908