Title :
Degradation of Acid Red B by the combined technology of ozonation and High-voltage pulsed discharge
Author :
Lian, Jing ; Guo, Yankai ; Yankai Guo ; Yang, Jingliang ; Kang, Li ; Yue, Lin ; Li, Haibo ; Wang, Yuyu
Author_Institution :
Sch. of Environ. Sci. & Eng., Hebei Univ. of Sci. & Technol., Shijiazhuang, China
Abstract :
In this study, the optimum conditions, the decolorization rate and the possible degradation mechanism were explored for the degradation of Acid Red B by the combined technology of ozonation and high voltage pulsed discharge (HVPD). The results suggested that the decolorization rate of the Acid Red B fitted the pseudo-first-order kinetics with initial dye concentration. The optimum ozone dose and pH was 4.0 g h-1 and 8.0, respectively. Compared to ozone alone, the combination of ozone and HVPD enhanced 25% of the decolorization rate. At the same time, a proposed degradation mechanism was put forward according to the degraded intermediates, which were analyzed by gas chromatography and mass spectrometry for nitrobenzene and benzene sulfonamide acid and were detected by ion chromatography for nitrate and sulfate ions and formic, acetic and oxalic acids. Therefore, the combined technology was a very promoting technology in the wastewater treatment.
Keywords :
biodegradable materials; chemical engineering; chromatography; discharges (electric); dyes; environmental degradation; high-voltage techniques; mass spectroscopy; ozonation (materials processing); pulsed power technology; reaction kinetics; wastewater treatment; Acid Red B degradation; benzene sulfonamide; decolorization rate; dye concentration; formic-acetic-oxalic acids; gas chromatography; high-voltage pulsed discharge; ion chromatography; mass spectrometry; nitrobenzene; optimum conditions; optimum ozone dose; ozonation; pseudofirst-order kinetics; wastewater treatment; Chemicals; Degradation; Discharges; Hazards; Inductors; Oxidation; Wastewater; Acid Red B; Decolorization; High-voltage pulsed discharge; Ozone;
Conference_Titel :
Remote Sensing, Environment and Transportation Engineering (RSETE), 2011 International Conference on
Conference_Location :
Nanjing
Print_ISBN :
978-1-4244-9172-8
DOI :
10.1109/RSETE.2011.5964251