Title :
A process to recycle thin film PV materials
Author :
Goozner, Robert E. ; Drinkard, William F. ; Long, Mark O. ; Byrd, Christi M.
Author_Institution :
Drinkard Metalox Inc., Charlotte, NC, USA
fDate :
29 Sep-3 Oct 1997
Abstract :
The wide scale interest in the commercial potential of cadmium telluride (CdTe) and copper indium diselenide (CIS) photovoltaic modules is tempered by the use of toxic metals such as cadmium and selenium in their manufacture. Drinkard Metalox has adapted hydrometallurgical technology to recycle CdTe cells. The process removes all the Cd and Te while, enabling reuse of substrates. Downstream processing recovers Te as metal from the lixivant, and removal of the lixivant leaves behind a pure Cd product. This process can also be utilized to process CIS cells. The lixivant will remove all the photoactive metals from the substrate of scrap CIS cells. A metallic stream of mixed Cu and Se metal is removed from the leachate by electrochemical methods. Subsequent processing will win purified Se
Keywords :
II-VI semiconductors; cadmium compounds; copper compounds; indium compounds; recycling; semiconductor thin films; solar cell arrays; ternary semiconductors; Cd; CdTe; Cu; CuInSe2; Drinkard Metalox; Se; Te; cadmium; cadmium telluride; copper indium diselenide; downstream processing; electrochemical methods; hydrometallurgical technology; lixivant; photoactive metals removal; photovoltaic modules; purified Se; recycling; selenium; substrates reuse; thin film PV materials; toxic metals; Cadmium compounds; Computational Intelligence Society; Copper; Indium; Photovoltaic systems; Recycling; Solar power generation; Substrates; Tellurium; Transistors;
Conference_Titel :
Photovoltaic Specialists Conference, 1997., Conference Record of the Twenty-Sixth IEEE
Conference_Location :
Anaheim, CA
Print_ISBN :
0-7803-3767-0
DOI :
10.1109/PVSC.1997.654295