Title :
GC/MS analyses of fractionated extraction of Yima coal with CS2, petroleum ether, benzene
Author :
Wang, Xiaohua ; Wei, Xianyong
Author_Institution :
Sch. of Chem. & Chem. Eng., Xi´´An Univ. of Sci. & Technol., Xi´´An, China
Abstract :
Yima coal was extracted with CS2, petroleum ether and benzene sequentially. The extracts were analyzed with GC/MS. It is presented that there are many biological markers in Yima coal, and the docyclic terpenoids have the most content in the extracts. Main components in CS2 soluble fraction from Yima coal are Aromatic terpenoids. Petroleum ether soluble fraction primarily consist of multi-carbon number n-alkanes. A series of diterpane evolution products with dehydroabietane skeleton and many oxygen-containing compounds were detected in benzene extract. The molecular structures detection of 1-bromotetracosane firstly provide information for existence form of halogeno-compounds in coal.
Keywords :
coal; fuel processing; separation; 1-bromotetracosane; CS2 soluble fraction; GC/MS analysis; Yima coal; aromatic terpenoids; benzene; biological markers; dehydroabietane skeleton; diterpane evolution products; docyclic terpenoids; fractionated extraction; halogeno-compounds; molecular structures detection; multicarbon number n-alkanes; oxygen-containing compounds; petroleum ether; Coal; Compounds; Data mining; Hydrocarbons; Solvents; GC/MS; chemical constituent; coal; solvent fractionated extraction;
Conference_Titel :
Remote Sensing, Environment and Transportation Engineering (RSETE), 2011 International Conference on
Conference_Location :
Nanjing
Print_ISBN :
978-1-4244-9172-8
DOI :
10.1109/RSETE.2011.5966130