DocumentCode
2714670
Title
Using rattling ions to probe sub-ps water network dynamics
Author
Schmidt, Diedrich A. ; Birer, Özgür ; Funkner, Stefan ; Born, Benjamin P. ; Gnanasekaran, Ramachandran ; Schwaab, Gerhard W. ; Leitner, David M. ; Havenith, Martina
Author_Institution
Dept. of Phys. Chem. II, Ruhr-Univ. Bochum, Bochum, Germany
fYear
2010
fDate
5-10 Sept. 2010
Firstpage
1
Lastpage
2
Abstract
We present THz measurements on fifteen solvated alkali halide salts using narrow band THz absorption and broad band THz Fourier transform spectroscopies in order to shed new light on the controversy of salts as kosmotropes (structure breakers) or chaotropes (structure makers).
Keywords
Fourier transform spectra; alkali metal halides; solvation; terahertz wave spectra; broadband terahertz Fourier transform spectroscopies; chaotropes; kosmotropes; narrow band terahertz absorption; rattling ions; solvated alkali halide salts; structure breakers; structure makers; subpicosecond water network dynamics; terahertz measurements; Absorption; Fourier transforms; Harmonic analysis; Ions; Mathematical model; Oscillators; Predictive models;
fLanguage
English
Publisher
ieee
Conference_Titel
Infrared Millimeter and Terahertz Waves (IRMMW-THz), 2010 35th International Conference on
Conference_Location
Rome
Print_ISBN
978-1-4244-6655-9
Type
conf
DOI
10.1109/ICIMW.2010.5612708
Filename
5612708
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