Title :
Terahertz Study of Chiral and Racemic Crystals
Author :
Franz, Morten ; Fischer, Bernd ; Abbott, Derek ; Helm, Hanspeter
Author_Institution :
Freiburg Univ., Freiburg
Abstract :
We studied far-infrared signatures of various molecules of biological importance using terahertz time-domain-spectroscopy. Spectral fingerprints in this frequency range are highly sensitive to the inter-and intra-molecular binding and long range order. As a consequence, phonon-Iike absorption modes differ, depending on whether a chiral or a racemic polycrystalline powder is used. In this contribution, we will present spectra of various chiral and racemic substances and discuss how our measurements could be used to gain a deeper understanding of inter-and intra-molecular binding.
Keywords :
infrared spectra; molecular biophysics; submillimetre wave spectra; biological molecules; chiral crystals; far-infrared signatures; inter-molecular binding; intra-molecular binding; phonon-Iike absorption modes; racemic crystals; racemic polycrystalline powder; spectral fingerprints; terahertz time-domain-spectroscopy; Absorption; Biomedical optical imaging; Bonding; Crystallization; Crystals; Frequency; Material properties; Optical sensors; Powders; Spectroscopy;
Conference_Titel :
Infrared Millimeter Waves and 14th International Conference on Teraherz Electronics, 2006. IRMMW-THz 2006. Joint 31st International Conference on
Conference_Location :
Shanghai
Print_ISBN :
1-4244-0400-2
Electronic_ISBN :
1-4244-0400-2
DOI :
10.1109/ICIMW.2006.368438