Investigation of Ni-based silicide formation by different dynamic surface annealing approaches

Sub-melt millisecond anneal (MSA) is one of major anneal techniques for forming ultra-shallow and highly activated junctions. Besides post-implant anneal for source/drain and source/drain extensions, MSA has also attracted increased interests in nickel-silicide formation recently. During the silicidation process, desired Ni diffusion in forming silicides is competing with un-wanted Ni diffusion along defects paths. The latter will cause higher junction leakage and/or source/drain leakage. Since the activation energy for the un-wanted diffusion is lower, higher process temperature with shorter duration is beneficial for minimizing the un-wanted diffusion. Furthermore, MSA allows high process temperature to be used for silicide formation, which can re-activate some dopants, such as arsenic and phosphors. These dopants are easily deactivated during lower temperature thermal processes post source/drain formation such as silicide block film deposition; therefore, transistor performance can be improved by using MSA for silicidation processes. In this work, dynamic surface annealing (DSA), which is one form of MSA techniques, was applied to form Ni-based silicides. The impacts of different combinations of soak RTA and DSA for thermal steps before and after selective nickel/NiSi strip were examined. One step DSA has been demonstrated effective reduction of Nickel piping by e-beam inspection count, improved NiSi resistance and junction leakage w/o device performance degradation.