Model-based electrochemical estimation of lithium-ion batteries

A linear Kalman filter based on a reduced order electrochemical model is designed to estimate internal battery potentials, concentration gradients, and state of charge (SOC) from external current and voltage measurements. The estimates are compared with results from an experimentally validated one-dimensional nonlinear finite volume model of a 6 Ah hybrid electric vehicle battery. The linear filter gives, to within ~2%, performance in the 30%-70% SOC range, except in the case of severe current pulses that draw electrode surface concentrations to near saturation and depletion; however, the estimates recover as concentration gradients relax. With 4 to 7 states, the filter has low order comparable to empirical equivalent circuit models but provides estimates of the batterypsilas internal electrochemical state.