Title :
Li diffusion in a composite electrode with internal fractal surface [Li-ion secondary cells]
Author_Institution :
Dept. of Chem. Technol., Delft Univ. of Technol., Netherlands
Abstract :
Lithium diffusion in the composite oxides is a key factor that determines the rate at which a battery can be charged and discharged. With increasing interest in higher power density, understanding the mechanisms of diffusion in insertion electrodes becomes important. The aim of the present work is investigation of Li content and roughness dependency of diffusivity by dynamic Monte Carlo simulation, in a 2D fractal model pore. An indentation model is illustrated
Keywords :
Monte Carlo methods; diffusion; electrochemical electrodes; electrochemistry; fractals; lithium; secondary cells; Li; Li diffusion; Li-ion secondary cells; battery charge/discharge rate; composite electrode; diffusivity; dynamic Monte Carlo simulation; insertion electrodes; internal fractal surface; power density; roughness; Amorphous materials; Batteries; Chemical technology; Composite materials; Electrodes; Equations; Fractals; Lithium; Postal services; Surface discharges;
Conference_Titel :
Applications and Advances, 2001. The Sixteenth Annual Battery Conference on
Conference_Location :
Long Beach, CA
Print_ISBN :
0-7803-6545-3
DOI :
10.1109/BCAA.2001.905117