Title :
Increasing the specific energy of deep-cycle VRLA batteries by improving material-utilization efficiencies
Author :
Arias, J.L. ; Boughn, D.W. ; Rowlette, J.J. ; Drake, E.D.
Author_Institution :
Bipolar Power Int. Inc., Whittier, CA, USA
Abstract :
Increasing the utilization efficiency of the active materials offers the greatest opportunity for improving the specific energy of deep-cycle VRLA batteries. Bipolar Power International (BPI) has been developing lead-sulfate-based high-utilization paste formulations for the past decade, as part of its bipolar-battery R&D program, Previous experiments with these pastes on both flat lead sheets (for bipolar plates) and cast grids have shown substantial improvements in material utilization efficiencies over traditional oxide-based pastes, together with good cycling performance. Recently, BPI has begun investigating the performance of its sulfate-based paste in reticulated Pb-metal foams as a means of further increasing utilization efficiency. The results of these preliminary experiments show improvements in positive-material utilization of at least 30% to 44% at the ½-hour to 10-hour rates, respectively, compared to traditional lead-oxide-based pastes on grids
Keywords :
electrochemical electrodes; electrochemistry; lead acid batteries; testing; 0.5 to 10 h; Pb; Pb-acid secondary cells; active materials utilisation efficiency; bipolar plates; bipolar-battery R&D program; cast grids; cycling performance; deep-cycle VRLA batteries; electrochemical performance; flat lead sheets; material-utilization efficiencies improvement; paste formulations; positive-material utilization; specific energy improvement; Batteries; Equations; Lead compounds; Microstructure; Research and development; Sheet materials;
Conference_Titel :
Applications and Advances, 2001. The Sixteenth Annual Battery Conference on
Conference_Location :
Long Beach, CA
Print_ISBN :
0-7803-6545-3
DOI :
10.1109/BCAA.2001.905128