DocumentCode
2923526
Title
Adsorption of NO (or NH3) +O2 over the Commercial SCR Catalyst Characterized by EPR
Author
Du Yun-gui ; Yun-tao, Li ; Qin, Zhong
Author_Institution
Coll. of Resources & Environ. Sci., Chongqing Univ., Chongqing, China
fYear
2011
fDate
19-20 Feb. 2011
Firstpage
1953
Lastpage
1956
Abstract
The adsorption of reactants over the commerciallized SCR catalyst surface was investigated by EPR, as well as the influence of H2O and SO2. The results showed that the V4+ over the catalyst could be oxidized under NO + O2 atmosphere, and NH3 was adsorbed on Brönsted acid sites. The amounts of V4+ and super oxide ions were promoted at the presence of H2O and SO2 after adsorption. However, the intensity of Fe3+ decreased when H2O and SO2 were present, indicating the favorable effect of Fe3+ for anti-poisoning.
Keywords
adsorption; catalysts; chemical technology; H2O; NO; SO2; anti-poisoning; commerciallized SCR catalyst surface; reactant adsorption; selective catalytic reduction; super oxide ion; Atmosphere; Commercialization; Ions; Temperature measurement; Thyristors; Water; X-ray scattering; EPR; commerciallized SCR catalyst; selective catalytic reduction (SCR);
fLanguage
English
Publisher
ieee
Conference_Titel
Computer Distributed Control and Intelligent Environmental Monitoring (CDCIEM), 2011 International Conference on
Conference_Location
Changsha
Print_ISBN
978-1-61284-278-3
Electronic_ISBN
978-0-7695-4350-5
Type
conf
DOI
10.1109/CDCIEM.2011.492
Filename
5748204
Link To Document