• DocumentCode
    2923526
  • Title

    Adsorption of NO (or NH3) +O2 over the Commercial SCR Catalyst Characterized by EPR

  • Author

    Du Yun-gui ; Yun-tao, Li ; Qin, Zhong

  • Author_Institution
    Coll. of Resources & Environ. Sci., Chongqing Univ., Chongqing, China
  • fYear
    2011
  • fDate
    19-20 Feb. 2011
  • Firstpage
    1953
  • Lastpage
    1956
  • Abstract
    The adsorption of reactants over the commerciallized SCR catalyst surface was investigated by EPR, as well as the influence of H2O and SO2. The results showed that the V4+ over the catalyst could be oxidized under NO + O2 atmosphere, and NH3 was adsorbed on Brönsted acid sites. The amounts of V4+ and super oxide ions were promoted at the presence of H2O and SO2 after adsorption. However, the intensity of Fe3+ decreased when H2O and SO2 were present, indicating the favorable effect of Fe3+ for anti-poisoning.
  • Keywords
    adsorption; catalysts; chemical technology; H2O; NO; SO2; anti-poisoning; commerciallized SCR catalyst surface; reactant adsorption; selective catalytic reduction; super oxide ion; Atmosphere; Commercialization; Ions; Temperature measurement; Thyristors; Water; X-ray scattering; EPR; commerciallized SCR catalyst; selective catalytic reduction (SCR);
  • fLanguage
    English
  • Publisher
    ieee
  • Conference_Titel
    Computer Distributed Control and Intelligent Environmental Monitoring (CDCIEM), 2011 International Conference on
  • Conference_Location
    Changsha
  • Print_ISBN
    978-1-61284-278-3
  • Electronic_ISBN
    978-0-7695-4350-5
  • Type

    conf

  • DOI
    10.1109/CDCIEM.2011.492
  • Filename
    5748204