Title :
Stabilized matrix for molten carbonate fuel cell
Author :
Nirasawa, Hitoshi ; Kawachi, Takanori ; Ogawa, Takashi ; Hori, Michio ; Tomimatsu, Norihiro ; Nakagawa, Kazuaki ; Ohzu, Hideyuki ; Yamazaki, Yohtaro
Author_Institution :
Lab. of Energy & Mech. Res., Toshiba R&D Center, Kawasaki, Japan
Abstract :
For commercialization of molten carbonate fuel cell (MCFC) power plants, the most important factors are MCFC performance and life. The performance and life of an MCFC depend on the electrolyte loss and gas crossover due to the matrix degradation, such as LiAlO2 particle growth during cell operation and the matrix cracking at the initial heat-up stage. In order to suppress the matrix degradation, we fabricated a stabilized matrix with α-LiAlO2 as the electrolyte support material and with long α-Al2O3 fibers as the reinforcement. We assembled the cell with the stabilized matrix. The performance of the cell is stable for 7000 hours. We consider that the matrix degradation, such as the particle growth during cell operation and matrix cracking, has not occurred in this cell
Keywords :
alumina; aluminium compounds; electric power generation; electrolytes; fuel cell power plants; fuel cells; lithium compounds; α-LiAlO2; 7000 h; Al2O3; LiAlO2; LiAlO2 particle growth; MCFC life; MCFC performance; MCFC power plants; cell operation; electrolyte loss; electrolyte support material; gas crossover; initial heat-up stage; long α-Al2O3 fibers; matrix cracking; matrix degradation; molten carbonate fuel cell; reinforcement; stabilized matrix; Assembly; Commercialization; Degradation; Fuel cells; Optical fiber testing; Organic materials; Performance loss; Power generation; Stability; Surface cracks;
Conference_Titel :
Energy Conversion Engineering Conference, 1996. IECEC 96., Proceedings of the 31st Intersociety
Conference_Location :
Washington, DC
Print_ISBN :
0-7803-3547-3
DOI :
10.1109/IECEC.1996.553867