• DocumentCode
    304312
  • Title

    Stabilized matrix for molten carbonate fuel cell

  • Author

    Nirasawa, Hitoshi ; Kawachi, Takanori ; Ogawa, Takashi ; Hori, Michio ; Tomimatsu, Norihiro ; Nakagawa, Kazuaki ; Ohzu, Hideyuki ; Yamazaki, Yohtaro

  • Author_Institution
    Lab. of Energy & Mech. Res., Toshiba R&D Center, Kawasaki, Japan
  • Volume
    2
  • fYear
    1996
  • fDate
    11-16 Aug 1996
  • Firstpage
    1132
  • Abstract
    For commercialization of molten carbonate fuel cell (MCFC) power plants, the most important factors are MCFC performance and life. The performance and life of an MCFC depend on the electrolyte loss and gas crossover due to the matrix degradation, such as LiAlO2 particle growth during cell operation and the matrix cracking at the initial heat-up stage. In order to suppress the matrix degradation, we fabricated a stabilized matrix with α-LiAlO2 as the electrolyte support material and with long α-Al2O3 fibers as the reinforcement. We assembled the cell with the stabilized matrix. The performance of the cell is stable for 7000 hours. We consider that the matrix degradation, such as the particle growth during cell operation and matrix cracking, has not occurred in this cell
  • Keywords
    alumina; aluminium compounds; electric power generation; electrolytes; fuel cell power plants; fuel cells; lithium compounds; α-LiAlO2; 7000 h; Al2O3; LiAlO2; LiAlO2 particle growth; MCFC life; MCFC performance; MCFC power plants; cell operation; electrolyte loss; electrolyte support material; gas crossover; initial heat-up stage; long α-Al2O3 fibers; matrix cracking; matrix degradation; molten carbonate fuel cell; reinforcement; stabilized matrix; Assembly; Commercialization; Degradation; Fuel cells; Optical fiber testing; Organic materials; Performance loss; Power generation; Stability; Surface cracks;
  • fLanguage
    English
  • Publisher
    ieee
  • Conference_Titel
    Energy Conversion Engineering Conference, 1996. IECEC 96., Proceedings of the 31st Intersociety
  • Conference_Location
    Washington, DC
  • ISSN
    1089-3547
  • Print_ISBN
    0-7803-3547-3
  • Type

    conf

  • DOI
    10.1109/IECEC.1996.553867
  • Filename
    553867