Title :
Electrical and thermal properties of polyvinyl acetal based nanocomposites
Author :
Polizos, G. ; Tuncer, E. ; Sauers, I. ; James, D.R. ; Ellis, A.R.
Author_Institution :
Fusion Energy Div., Oak Ridge Nat. Lab., Oak Ridge, TN, USA
Abstract :
A water chemistry procedure is used to synthesize titanium dioxide nanoparticles which can later be blended with a polymer to form a nanodielectric. The synthesized nanoparticles are dispersed in two grades of polyvinyl acetal (commercially available under the trade names BX-L and KS-10, manufactured by SEKISUI Chemicals). Nanocomposite materials were prepared with 15 and 33 wt% titanium dioxide. The variation of the glass transition temperature with increasing filler weight fraction is presented. The dielectric breakdown strengths of the nanodielectric samples are reported. The presented results can be employed to optimize the dielectric properties of the studied nanocomposites for potential use in cryogenic high voltage applications.
Keywords :
dielectric materials; electric breakdown; filled polymers; glass transition; nanocomposites; nanofabrication; nanoparticles; titanium compounds; TiO2; dielectric breakdown strengths; electrical properties; filler weight fraction; glass transition temperature; nanocomposites; nanodielectric; polymer; polyvinyl acetal; thermal properties; titanium dioxide nanoparticles; water chemistry; Chemicals; Chemistry; Dielectric materials; Glass; Manufacturing; Nanocomposites; Nanoparticles; Polymers; Temperature; Titanium;
Conference_Titel :
Electrical Insulation and Dielectric Phenomena, 2009. CEIDP '09. IEEE Conference on
Conference_Location :
Virginia Beach, VA
Print_ISBN :
978-1-4244-4557-8
Electronic_ISBN :
0084-9162
DOI :
10.1109/CEIDP.2009.5377754