• DocumentCode
    3143189
  • Title

    Phase T,x-diagram of Pb1-xCaxTiO3 single crystals

  • Author

    Eremkin, V.V. ; Smotrakov, V.G. ; Balyunis, L.E. ; Shevtsova, S.I. ; Kozakov, A.T.

  • Author_Institution
    Inst. of Phys., Rostov State Univ., Russia
  • fYear
    1991
  • fDate
    33457
  • Firstpage
    97
  • Lastpage
    100
  • Abstract
    Phase T,x-diagram of the Pb1-xCaxTiO3 (0⩽x⩽0.62) solid solution system has been constructed in the range from room temperature to 770 K using data of single crystal optical studies and X-ray microanalysis. Besides the typical for PbTiO 3 ferroelectric tetragonal and paraelectric cubic phases, two ferro- and non-ferroelectric ones having the pseudomonoclinic unit cell distortions also as two additional tetragonal phases, at least one of which is confidently non-ferroelectric, have been found and their exact stability limits have been determined
  • Keywords
    X-ray diffraction; calcium compounds; crystal structure; ferroelectric materials; ferroelectric transitions; lead compounds; phase diagrams; (PbCa)TiO3; 20 C to 770 K; Pb1-xCaxTiO3; X-ray microanalysis; exact stability limits; ferroelectric; nonferroelectric phase; optical studies; paraelectric cubic phase; phase (T,x) diagram; pseudomonoclinic unit cell distortions; tetragonal; Calcium; Ceramics; Crystalline materials; Crystals; Ferroelectric materials; Lattices; Optical distortion; Prototypes; Solids; Temperature;
  • fLanguage
    English
  • Publisher
    ieee
  • Conference_Titel
    Applications of Ferroelectrics, 1994.ISAF '94., Proceedings of the Ninth IEEE International Symposium on
  • Conference_Location
    University Park, PA
  • Print_ISBN
    0-7803-1847-1
  • Type

    conf

  • DOI
    10.1109/ISAF.1994.522307
  • Filename
    522307