Optimization of sythesis conditions of 1,1´ ferrocenedimethanol

Author

Ming, Chang-xin ; Han, Jian-Rong ; Wang, Wei ; Li, Zhen-chao ; Tian, Xia

Author_Institution

Coll. of Sci., Hebei Univ. of Sci. & Technol., Shijiazhuang, China

fYear

2011

fDate

16-18 April 2011

Firstpage

5105

Lastpage

5107

Abstract

The synthetical conditions of 1,1´-ferrocene-dimethanol were investigated using 1,1´-ferrocenedicarboxylic acid as raw material. The effects of the component ratio, solvent, reaction temperature, time on the product yield have been discussed and the optimum technological conditions have been obtained. using 1,4-dioxane as solvent, the ratio of n(dicarboxylic acid):n(LiAlH₄)=1:10, reaction time 4.0h, reaction temperature 90°C, The product yield was 89.9%.

Keywords

chemical engineering; materials preparation; organometallic compounds; reaction kinetics; solvent effects; 1,1´ ferrocenedimethanol; 1,1´-ferrocenedicarboxylic acid; 1,4-dioxane; component ratio effects; product yield; reaction temperature effects; reaction time effects; solvent effects; sythesis condition optimization; temperature 90 degC; time 4 hr; Aluminum; Compounds; Instruments; Lithium; Materials; Solvents; System-on-a-chip; 1,1´-ferrocenedicarboxylic acid; 1,1´-ferrocenedimetha-nol; LiAlH4; Reduction; Synthesis;

fLanguage

English

Publisher

ieee

Conference_Titel

Consumer Electronics, Communications and Networks (CECNet), 2011 International Conference on

Conference_Location

XianNing

Print_ISBN

978-1-61284-458-9

Type

conf

DOI

10.1109/CECNET.2011.5768454

Filename

5768454