Title :
Transition metals-Modified SAPO-34 for methanol conversion to light olefins
Author :
Jie Mi ; Fenyun Yuan ; Jianan Zhang
Author_Institution :
Key Lab. of Coal Sci. & Technol. of Shanxi Province & Minist. of Educ., Taiyuan Univ. of Technol., Taiyuan, China
Abstract :
The catalysts prepared by modifying SAPO-34 molecular sieve catalyst with Transition metals (Zn, Ni, Co, and Fe) by hydrothermal method were investigated for methanol conversion to light olefins (MTO). And the prepared catalysts were characterized by XRD and SEM. The catalytic properties of the modified molecular sieves were evaluated through a fixed bed reactor. The results showed that the ethylene yield of ZnSAPO-34 was increased by 3.2% and total yield of ethylene and propylene was increased by 5.0%.
Keywords :
X-ray diffraction; catalysis; catalysts; chemical reactors; crystal growth from solution; scanning electron microscopy; MTO; SAPO-34 molecular sieve catalyst; SEM; XRD; catalytic properties; ethylene yield; fixed bed reactor; hydrothermal method; light olefins; methanol conversion; modified molecular sieves; propylene; transition metals; Diffraction; Inductors; Methanol; Molecular sieves; X-ray diffraction; Zinc; SAPO-34; hydrothermal method; methanol to olefins; transition metal; yield;
Conference_Titel :
Materials for Renewable Energy and Environment (ICMREE), 2013 International Conference on
Conference_Location :
Chengdu
Print_ISBN :
978-1-4799-3335-8
DOI :
10.1109/ICMREE.2013.6893778