Theoretical and experimental analysis of a 3-volt lithium/polymer rechargeable battery

Author

Fellner, Joseph P. ; Sandhu, Sarwan S.

Author_Institution

Res. & Dev. Center, Wright-Patterson AFB, OH, USA

Volume

1

fYear

1997

fDate

27 Jul-1 Aug 1997

Firstpage

25

Abstract

The cell voltage and discharge capacity as a function of discharge rate for a room temperature rechargeable lithium/polymer electrolyte/lithium manganese oxide cell can be accurately simulated by a simple diffusion-limited reaction model and by a transient, two dimensional mass transfer and generation model. The importance of using the intrinsic lithium chemical diffusion coefficient in modeling lithium insertion cathode materials is addressed

Keywords

cathodes; electrochemical electrodes; electrochemistry; lithium; lithium compounds; manganese compounds; mass transfer; polymers; secondary cells; solid electrolytes; 2-D transient mass transfer/generation model; 3 V; Li-LiMn₂O₄; Li-LiMn₂O₄ secondary battery; cell voltage; diffusion-limited reaction model; discharge capacity; discharge rate; intrinsic lithium chemical diffusion coefficient; lithium insertion cathode materials; polymer electrolyte; Anodes; Batteries; Cathodes; Chemicals; Conducting materials; Conductivity; Electrodes; Lithium; Manganese; Polymers;

fLanguage

English

Publisher

ieee

Conference_Titel

Energy Conversion Engineering Conference, 1997. IECEC-97., Proceedings of the 32nd Intersociety

Conference_Location

Honolulu, HI

Print_ISBN

0-7803-4515-0

Type

conf

DOI

10.1109/IECEC.1997.659152

Filename

659152