Title :
Nano porous silicon membrane with channels for micro direct methanol fuel cells
Author :
Wang, Mei ; Wang, Xiaohong ; Wu, Shan ; Tan, Zhimin ; Liu, Litian ; Guo, Xun
Author_Institution :
Tsinghua Nat. Lab. for Inf. Sci. & Technol., Tsinghua Univ., Beijing, China
Abstract :
In this paper, we demonstrate a Nafion® filled porous silicon membrane with channels as proton exchange membrane (PEM) for micro direct methanol fuel cell (μDMFC). Nafion® filled nano porous silicon membranes with thickness of 60um have proton conductivities (0.02S/cm ~ 0.03S/cm) comparable to the Nafion® membrane (0.05S/cm) which is the most commonly used commercial PEM material. The serpentine channels fabricated by KOH etching are used to provide the fuel and oxygen. Thank to these techniques, a compact structure μDMFC that integrates anode plate, cathode plate and membrane electrode assembly (MEA) on a single layer can be achieved. The new μDMFC based on the nano porous silicon membrane can make the encapsulation and integration with micro electromechanical system easier.
Keywords :
anodes; direct methanol fuel cells; electrochemical electrodes; elemental semiconductors; micromechanical devices; nanoporous materials; silicon; μDMFC; KOH etching; MEA; Nafion filled porous silicon membrane; PEM material; anode plate; cathode plate; membrane electrode assembly; microdirect methanol fuel cells; microelectromechanical system; nanoporous silicon membrane; proton conductivities; proton exchange membrane; serpentine channels; size 60 mum; Conductivity; Etching; Fuel cells; Methanol; Protons; Scanning electron microscopy; Silicon; Nafion®; micro direct methanol fuel cell; porous silicon; proton exchange membrane;
Conference_Titel :
Nano/Micro Engineered and Molecular Systems (NEMS), 2011 IEEE International Conference on
Conference_Location :
Kaohsiung
Print_ISBN :
978-1-61284-775-7
DOI :
10.1109/NEMS.2011.6017516