Silica Supported Barium Chloride (SiO2-BaCl2): Efficient and Heterogeneous catalyst for the environmentally friendly preparation of N,N′-alkylidene bisamides under solvent-free condition

Author

Shafiee, Mohammad Reza Mohammad ; Zakaria, Mohamad Pauzi ; Azar, Parviz Aberomand

Author_Institution

Forensic Chem. Res. Group (FCRG), Univ. Putra Malaysia, Serdang, Malaysia

fYear

2010

fDate

2-4 Nov. 2010

Firstpage

172

Lastpage

175

Abstract

A series of N,N´-alkylidene bisamides were prepared via a green and environmentally friendly synthetic protocol from the reaction of phenyl acetylene/1-Hexyne, aromatic aldehyde and benzamide/acetamide. Silica Supported Barium Chloride (SiO₂-BaCl₂) catalyzes the reaction. The prepared catalysts were characterized by X-ray diffraction. The products were obtained with high conversion and yields.

Keywords

X-ray diffraction; barium compounds; catalysis; chemical engineering; environmental factors; organic compounds; N,N´-alkylidene bisamides; SiO₂-BaCI₂; X-ray diffraction; acetamide; aromatic aldehyde; benzamide; environmentally friendly synthetic protocol; heterogeneous catalyst; phenyl acetylene-1-Hexyne; silica supported barium chloride; solvent free condition; Argon; Compounds; Green products; ISO standards; Petroleum; Environmentally Friendly synthesis; Heterogeneous Catalyst; N,N′-alkylidene bisamides; SiO2-BaCl2;

fLanguage

English

Publisher

ieee

Conference_Titel

Chemical, Biological and Environmental Engineering (ICBEE), 2010 2nd International Conference on

Conference_Location

Cairo

Print_ISBN

978-1-4244-8748-6

Electronic_ISBN

978-1-4244-8749-3

Type

conf

DOI

10.1109/ICBEE.2010.5650087

Filename

5650087