Title :
Studying phase equilibrium liquid-vapor in the system UF/sub 6/-BRF/sub 3/ with 343.15 and 353.15 K
Author :
Ostvald, R.V. ; Zherin, I.I. ; Usov, V.F.
Author_Institution :
Tomsk Polytech. Inst., Russia
Abstract :
The given paper studies the liquid-vapor phase equilibrium in the system UF6-BrF3 under temperatures of 343.15 and 353.15 K. For the experiments, bromine trifluoride and industrial uranium hexafluoride were used. Cleaning UF6 and BrF3 from HF was performed by long low-temperature vacuum distillation laws of phase equilibria. Thus, the thermodynamic analysis of experimental and calculated data by the phase equilibriums liquid-vapor in the system UF6-BrF3 at the temperatures 343.15 K and 353.15 K revealed their conformity to main laws of phase equilibriums. Obtained experimental data show the capability of dividing the considered system into pure components by the methods of distillation and rectification.
Keywords :
bromine compounds; distillation; fission reactor fuel; phase equilibrium; uranium compounds; vapour pressure; 343.15 K; 353.15 K; BrF3; UF6; bromine trifluoride; industrial uranium hexafluoride; low-temperature vacuum distillation; phase equilibrium liquid-vapor; rectification methods; thermodynamic analysis; Control system synthesis; Equations; Hafnium; Isothermal processes; Nuclear fuels; Nuclear thermodynamics; Phase measurement; Pressure control; Temperature control; Temperature dependence;
Conference_Titel :
Modern Techniques and Technologies, 2003. MTT 2003. Proceedings of the 9th International Scientific and Practical Conference of Students, Post-graduates and Young Scientists
Conference_Location :
Tomsk
Print_ISBN :
0-7803-7669-2
DOI :
10.1109/SPCMTT.2003.1438211