Title :
Polaronic effects in disordered dielectrics
Author_Institution :
Herzen State Pedgagical Univ., St. Petersburg, Russia
Abstract :
A number of experimental techniques for distinguishing small-polaronic hops from nonpolaronic hops in disordered dielectrics are presented. It is shown that the temperature and field dependencies of DC conductivity provide an indication of the small-polaronic (ultrasmall polarons) hops. For small-polaronic hops, a field dependence of DC conductivity exhibits a section where σ decreases with E prior to exponential increase in σ. In the case of substances with ultrasmall polarons the temperature dependence of the electrical conductivity can be represented in the form ln (σT3/2)~T. The strong field polaronic effects take place in the lower frequency range up to boundary frequency which temperature dependence is determined by electron-lattice coupling strength. These results are in accord with observations in amorphous tantalum oxide for which there is explicit evidence of small-polaronic hopping
Keywords :
amorphous state; dielectric materials; hopping conduction; small polaron conduction; tantalum compounds; DC conductivity; Ta2O5; amorphous tantalum oxide; disordered dielectric; electron-lattice coupling strength; nonpolaronic hopping; small-polaronic hopping; ultrasmall polarons; Absorption; Amorphous materials; Dielectric measurements; Frequency; Lattices; Phonons; Resonance; Temperature dependence; Thermal conductivity; Wave functions;
Conference_Titel :
Electrets, 1996. (ISE 9), 9th International Symposium on
Conference_Location :
Shanghai
Print_ISBN :
0-7803-2695-4
DOI :
10.1109/ISE.1996.578050