Title :
Notice of Retraction
Reductive Sorption of Heavy Metals from Aqueous Solutions on a Carbonaceous Sorbent Chemically Prepared from Date Palm Leaflets
Author :
El-Shafey, E.I. ; Al-Haddabi, K.N.
Author_Institution :
Dept. of Chem., Sultan Qaboos Univ., Muscat, Oman
Abstract :
Notice of Retraction
After careful and considered review of the content of this paper by a duly constituted expert committee, this paper has been found to be in violation of IEEE´s Publication Principles.
We hereby retract the content of this paper. Reasonable effort should be made to remove all past references to this paper.
The presenting author of this paper has the option to appeal this decision by contacting TPII@ieee.org.
A carbonaceous sorbent was prepared from date palm leaflets via sulfuric acid treatment. The ability of the prepared sorbent to remove Hg(II) (chloride media) and Pb(II) (nitrate media) from aqueous solutions was investigated by following the influence of various parameters such as contact time, pH, metal ion concentration and temperature. Kinetics data followed a pseudo second order rate expression for both metals with a much faster sorption for Pb(II) than for Hg(II). Sorption was low at low initial pH and increases as pH increases with a decrease in the final pH indicating protons release in solution and ion exchange mechanism. Equilibrium data were found to fit well the Langmuir equation with increased sorption as temperature rises. Hg(II) was reduced to the insoluble Hg2Cl2 crystals on the sorbent surface indicating Hg(II) reduction.
Keywords :
chemical engineering; hazardous materials; ion exchange; reduction (chemical); sorption; sulphur compounds; toxicology; wastewater treatment; Langmuir equation; aqueous solutions; carbonaceous sorbent; date palm leaflets; heavy metals; ion exchange; kinetics; pseudo second order rate expression; reductive sorption; sulfuric acid treatment; Carbon; Crystals; Ions; Kinetic theory; Metals; Surface treatment; X-ray diffraction;
Conference_Titel :
Bioinformatics and Biomedical Engineering, (iCBBE) 2011 5th International Conference on
Conference_Location :
Wuhan
Print_ISBN :
978-1-4244-5088-6
DOI :
10.1109/icbbe.2011.5781067