Title :
Notice of Retraction
Photocatalytic Degradation of Organic Pollutant in Water by Iron Doped Mesoporous TiO2 Prepared via Modified Sol-Gel Process
Author :
Shaozheng Hu ; Fayun Li ; Zhiping Fan ; Anjie Wang
Author_Institution :
Inst. of Eco-Environ. Sci., Liaoning Univ. of Pet. & Chem. Technol., Fushun, China
Abstract :
Notice of Retraction
After careful and considered review of the content of this paper by a duly constituted expert committee, this paper has been found to be in violation of IEEE´s Publication Principles.
We hereby retract the content of this paper. Reasonable effort should be made to remove all past references to this paper.
The presenting author of this paper has the option to appeal this decision by contacting TPII@ieee.org.
TiO2 photocatalysis technology has been widely used in environmental remediation, especially for wastewater treatment technology. In this paper, Fe3+ doped mesoporous TiO2 was prepared via modified sol-gel process using MCM-41 as hard template. The photocatalytic activities of prepared samples were tested in the degradation of an aqueous solution of a reactive dyestuff, methylene blue, under visible light. The obtained samples were characterized by X-ray diffraction, N2 adsorption, FT-IR, and UV-Vis spectroscopy. The prepared Fe3+ doped TiO2 was pure anatase phase when the calcination temperature below 700°C. The Ti-O-Si bond formed between TiO2 and MCM-41 fixed the TiO2 on the MCM-41 surface which restricted the agglomeration and growth of the TiO2 particles. Fe3+ was doped by replacing the Ti4+ in TiO2 lattice, which introduced a new energy level (Fe3+/Fe4+) into the band gap, thus increased the absorption in visible light region. The addition of MCM-41 during the preparation procedure greatly improved the photocatalytic activity of prepared TiO2 catalysts. The calcination temperature played an important role in affecting the photocatalytic activity.
Keywords :
Fourier transform spectra; X-ray diffraction; adsorption; calcination; catalysis; dyes; infrared spectra; iron; photochemistry; sol-gel processing; titanium compounds; ultraviolet spectra; visible spectra; wastewater treatment; water pollution; FT-IR; Fe3+; MCM-41; TiO2; UV-Vis spectroscopy; X-ray diffraction; absorption; adsorption; agglomeration; anatase phase; aqueous solution degradation; band gap; calcination temperature; catalysts; energy level; environmental remediation; hard template; iron doped mesoporous titanium dioxide; methylene blue; modified sol-gel process; organic pollutant; photocatalysis technology; photocatalytic activity; photocatalytic degradation; preparation procedure; reactive dyestuff; visible light region; wastewater treatment technology; Calcination; Degradation; Hafnium; Iron; Mesoporous materials; Photonic band gap;
Conference_Titel :
Bioinformatics and Biomedical Engineering, (iCBBE) 2011 5th International Conference on
Conference_Location :
Wuhan
Print_ISBN :
978-1-4244-5088-6
DOI :
10.1109/icbbe.2011.5781085