Title :
Notice of Retraction
The Study of the Machanism of Iron-Based Transition State Oxides Catalytic Oxidative Desulfurization
Author :
He Zhiqiang ; Liu Jingrong
Author_Institution :
Inner Mongolia Electr. Power Sci. Res. Inst., Inner Mongolia Univ. of Technol., Huhhot, China
Abstract :
Notice of Retraction
After careful and considered review of the content of this paper by a duly constituted expert committee, this paper has been found to be in violation of IEEE´s Publication Principles.
We hereby retract the content of this paper. Reasonable effort should be made to remove all past references to this paper.
The presenting author of this paper has the option to appeal this decision by contacting TPII@ieee.org.
The mechanism of Fe3+catalyzed oxidation of S(IV) is the combination of catalyzed oxidation and radical reaction, the O2- produced from the oxygen in solution plays a very important role for the oxidation of S(IV),which determines the mode and process of the reaction. In the absence of catalyst, the oxidation of S(IV) is relatively slow in the liquid, the reaction rate depends on the concentration of dissolved oxygen. When pH is 2.80, the reaction rate constant of Fe3+ catalyzed oxidation of S(IV) is 588 (mol / L)-1 · s-1.). The study results confirmed that Fe3+ has a strong oxidation effect on S(IV). By maintaining the concentration of Fe3+ and dissolved oxygen in the liquid, we can get a stable desulphurization efficiency.
Keywords :
catalysis; catalysts; chemical engineering; chemical reactions; dissolving; fuel desulphurisation; iron; oxidation; Fe; catalytic oxidative desulfurization; dissolved oxygen; iron-based transition state oxides; radical reaction; Compounds; Equations; Iron; Kinetic theory; Mathematical model; Oxidation;
Conference_Titel :
Bioinformatics and Biomedical Engineering, (iCBBE) 2011 5th International Conference on
Conference_Location :
Wuhan
Print_ISBN :
978-1-4244-5088-6
DOI :
10.1109/icbbe.2011.5781291