Title :
Synthesis and evaluation of thermoelectric multilayer films
Author :
Wagner, Andrew V. ; Foreman, Ronald J. ; Summers, Leslie J. ; Barbee, Troy W. ; Farmer, Joseph C.
Author_Institution :
Dept. of Chem. & Mater. Sci., Lawrence Livermore Nat. Lab., CA, USA
Abstract :
The deposition of compositionally-modulated (Bi/sub 1-x/Sb/sub x/)/sub 2/(Te/sub 1-y/Se/sub y/)/sub 3/ thermoelectric multilayer films by magnetron sputtering has been demonstrated. Structures with a period of 140 /spl Aring/ are shown to be stable to interdiffusion at the high deposition temperatures necessary for growth of single-layer crystalline films with ZT>0.5. These multilayers are of the correct dimension to exhibit the electronic properties of quantum well structures. Furthermore it is shown that the Seebeck coefficient of the films is not degraded by the presence of this multilayer structure. It may be possible to synthesize a multilayer thermoelectric material with enhanced ZT by maximizing the barrier height through optimization of the composition of the barrier.
Keywords :
Seebeck effect; bismuth compounds; chemical interdiffusion; semiconductor growth; semiconductor materials; semiconductor superlattices; semiconductor thin films; sputtered coatings; surface diffusion; thermoelectric power; (Bi/sub 1-x/Sb/sub x/)/sub 2/(Te/sub 1-y/Se/sub y/)/sub 3/; (BiSb)/sub 2/(TeSe)/sub 3/; 140 A; Seebeck coefficient; barrier height; deposition; interdiffusion; magnetron sputtering; thermoelectric multilayer films; Bismuth; Composite materials; Crystallization; Degradation; Magnetic multilayers; Nonhomogeneous media; Sputtering; Tellurium; Temperature; Thermoelectricity;
Conference_Titel :
Thermoelectrics, 1996., Fifteenth International Conference on
Conference_Location :
Pasadena, CA, USA
Print_ISBN :
0-7803-3221-0
DOI :
10.1109/ICT.1996.553527
