Title :
Dielectric behaviour and thermostimulated current of copolymer of vinylidene fluoride and trifluoroethylene
Author :
Wen, Jiamun ; Dong, Yong
Author_Institution :
Inst. of Org. Chem., Acad. Sinica, Shanghai, China
Abstract :
The dielectric behavior and thermostimulated current have been investigated in the 77/23 and 56/44 mol% copolymers of vinylidene fluoride and trifluoroethylene which were polarized under different conditions. The peak Tm is melting point of the copolymers. The peak ρ is due to the depolarization of the space change. The Tc is the Curie point of the ferroelectric polymers. The peak α0 may be attributed to the molecular motion in crystalline regions. The peaks β and γ correspond to the glassy transition and local mode relaxation in amorphous regions, respectively
Keywords :
dielectric depolarisation; dielectric polarisation; ferroelectric materials; polymer blends; polymer films; space charge; thermally stimulated currents; Curie point; amorphous region; crystalline region; dielectric polarization; ferroelectric polymer; glassy transition; local mode relaxation; melting point; molecular motion; space change depolarization; thermostimulated current; vinylidene fluoride trifluoroethylene copolymer; Amorphous materials; Crystallization; Dielectric losses; Dielectric measurements; Ferroelectric materials; Heating; Polarization; Polymers; Pyroelectricity; Temperature;
Conference_Titel :
Electrets, 1996. (ISE 9), 9th International Symposium on
Conference_Location :
Shanghai
Print_ISBN :
0-7803-2695-4
DOI :
10.1109/ISE.1996.578246