The structure of ion-dipole clusters in solutions of polar admixture in non-polar liquids

Author

Zhakin, A.I.

Author_Institution

Dept. of Theor. & Exp. Phys., Kursk State Tech. Univ., Kursk, Russia

fYear

1996

fDate

15-19 Jul 1996

Firstpage

97

Lastpage

98

Abstract

The solution of polar admixture (nitrobenzene, bytanol etc) in non-polar liquid dielectrics (transformer oil, bytanol, etc) are the example of the liquids where the electrochemical injection on the electrode interfaces can be controlled. Some of these reactions can be reproductive that is important for applications. The experiments had shown that major role in the conductivity of these media plays the ion-dipole clusters (IDS). They are close to small particles than to molecular complexes and their sizes have an order about 100 A. In this work we study the structure of IDC by statistical method and calculate the effective radius and coverage charge of IDC

Keywords

dielectric liquids; liquid mixtures; liquid structure; solutions; butanol; electrochemical injection; electrode interface; ion-dipole clusters; nitrobenzene; nonpolar liquid dielectric; polar admixture; solution; structure; transformer oil; Cellular neural networks; Charge measurement; Current measurement; Dielectric liquids; Equations; Intrusion detection; Joining processes; Oil insulation; Protons; Q measurement;

fLanguage

English

Publisher

ieee

Conference_Titel

Conduction and Breakdown in Dielectric Liquids, 1996, ICDL '96., 12th International Conference on

Conference_Location

Roma

Print_ISBN

0-7803-3560-0

Type

conf

DOI

10.1109/ICDL.1996.565329

Filename

565329