Title :
Structure and reductive dechlorination of supported nano Cu/Fe bimetal
Author :
Zhang Huan ; Zheng Yingxue ; Jin Zhaohui
Author_Institution :
Dept. of Environ. & Chem., Tianjin Polytech. Univ., Tianjin, China
Abstract :
Supported nano Cu/Fe bimetal was prepared by using KBH4 as the reducing agent when micro-scale graphite as a support material. This supported nano bimetal showed the well reductive chlorination to trichloroethylene(TCE) in the solution. The nano Cu/Fe with spherical particle and spherical nanocluster structure were synthesized in the H2O and ethanol/H2O system respectively. The size of spherical nano Cu/Fe was non-uniformly when the Fe2+ concentration was 0.02mol/L during the synthesizing. And the Cu/Fe with spherical nanocluster had the uniformly sphere shape while the Fe2+ concentration was 0.05mol/L. When the Fe2+ concentration was 0.2mol/L, bimetal had the nano whisker shape. The experiment results showed that the nano Cu/Fe bimetals which were synthesized in the ethanol/H2O system and the Fe2+ concentration was 0.05mol/L had the fastest dechlorination rate on TCE.
Keywords :
bimetals; copper; graphite; iron; nanostructured materials; water treatment; KBH4; TCE; ethanol-H2O system; microscale graphite; nano Cu-Fe bimetal; reductive dechlorination; spherical nanocluster structure; spherical particle; structure dechlorination; trichloroethylene; Active matrix organic light emitting diodes; Aggregates; Biomembranes; Chemistry; Degradation; Ethanol; Iron; Nanostructures; Shape; Water; Cu/Fe bimetal; reductive dechlorination; structure; supported;
Conference_Titel :
Mechanic Automation and Control Engineering (MACE), 2010 International Conference on
Conference_Location :
Wuhan
Print_ISBN :
978-1-4244-7737-1
DOI :
10.1109/MACE.2010.5536533
