Preparation of modified chitosan by salicylaldehyde

Author

Yewei Du ; Juanqin Xue ; Yunfeng Xue ; Dandan Wen ; Xiaona Ma

Author_Institution

Sch. of Metall. & Eng., Xi´an Univ. of Archit. & Technol., Xi´an, China

Volume

6

fYear

2011

fDate

12-14 Aug. 2011

Firstpage

2908

Lastpage

2911

Abstract

The salicylaldehyde was used as monomer to modify chitosan. The resin material is characterized by means of IR. In ethanol solvent, Schiff base reaction between chitosan and salicylaldehyde was carried out, the salicylicaldehyde grafted chitosan (S-CTS) was generated. The effects of the reaction temperature, the reaction time, the reactant ratio, the system pH and the stirring rate on the graft reaction rate are studied in detail. The rersults show that the best reaction conditions are as follows: the temperature is 60°C, the reaction time is 8h, the ratio of chitosan and salicylaldehyde is 1:4, the pH is 5 and the stirring rate is 440r/min, the grafting rate can achieve 37.5%.

Keywords

chemical engineering; chemical reactions; resins; solvents (industrial); Schiff base reaction; chitosan preparation; ethanol solvent; monomer; reactant ratio; reaction temperature; reaction time; resin material; salicylaldehyde; stirring rate; temperature 60 degC; time 8 h; Chemicals; Ethanol; Materials; Optical filters; Presses; Spectroscopy; Temperature distribution; IR; chitosan; grafting; salicyladehyde;

fLanguage

English

Publisher

ieee

Conference_Titel

Electronic and Mechanical Engineering and Information Technology (EMEIT), 2011 International Conference on

Conference_Location

Harbin, Heilongjiang, China

Print_ISBN

978-1-61284-087-1

Type

conf

DOI

10.1109/EMEIT.2011.6023656

Filename

6023656