Title :
Application of phosphonium montmorillonites in polypropylene/MH flame retardant system
Author :
Xiang, Cai ; Biao, Yu ; Xianshen, Zeng ; Shaozao, Tan
Author_Institution :
Dept. of Chem., Jinan Univ., Guangzhou, China
Abstract :
This paper studied the preparation and effects of phosphonium montmorillonites (P-MMT) on flame retardance and thermal stability of the flame retardant system consisting of polypropylene (PP) and magnesium hydroxide. P-MMT were prepared by introducing hexadecyl tributyl phosphonium bromide into sodium montmorillonite through ion-exchange method. The flame residence data indicate that the heat release rate of system can be reduced from 226.7 kW/m2 to 204.4 kW/m2 by adding P-MMT and the MHRR360 from 167.6 kW/m2 to 138.3 kW/m2. The introduction of P-MMT can effectively promote the flame retardance of the system.
Keywords :
Ceramics; Chemistry; Fires; Flame retardants; ISO standards; Magnesium compounds; Nanocomposites; Polymers; Thermal stability; X-ray scattering; component; flame retardance; magnesium hydroxide; phosphonium montmorillonites; polypropylene; synergistic effect;
Conference_Titel :
Mechanic Automation and Control Engineering (MACE), 2010 International Conference on
Conference_Location :
Wuhan, China
Print_ISBN :
978-1-4244-7737-1
DOI :
10.1109/MACE.2010.5536636