Electric-field-induced phase switching in textured Ba-doped bismuth ferrite lead titanate

Author

Palizdar, Meghdad ; Comyn, T.P. ; Stevenson, Tim J. ; Walshaw, Richard ; Poterala, Stephen F. ; Messing, Gary L. ; Suvaci, Ender ; Kleppe, Annette P. ; Jehcoat, Andrew J. ; Bell, Andrew J.

Author_Institution

Inst. for Mater. Res., Univ. of Leeds, Leeds, UK

fYear

2013

fDate

21-25 July 2013

Firstpage

138

Lastpage

140

Abstract

The template grain growth technique was used to synthesis textured 60BiFeO₃-PbTiO₃ (60:40BFPT) by using platelets of BaTiO₃ as template. Synchrotron measurement clearly showed textured 60:40BFPT. Moreover, in situ high energy synchrotron radiation was employed to investigate the influence of an external electric filed on crystallographic structure of mixed phase 60:40BFPT. Application of an electric field ≥ 1 kV/mm resulted in phase transformation from mixed rhombohedral/tetragonal phases (≈ 73.5% tetragonal / 26.5% rhombohedral) to predominately tetragonal phase (≈ 95%) at applied field of 6 kV/mm.

Keywords

antiferromagnetic materials; barium compounds; bismuth compounds; crystal structure; grain growth; lead compounds; magnetoelectric effects; piezoelectric materials; solid-state phase transformations; texture; BiFeO₃-PbTiO₃-BaTiO₃; crystallographic structure; electric-field-induced phase switching; external electric filed; in energy synchrotron radiation; mixed rhombohedral/tetragonal phases; phase transformation; synchrotron measurement; template grain growth technique; tetragonal phase; textured Ba-doped bismuth ferrite lead titanate; Crystals; Diffraction; Educational institutions; Electric fields; Synchrotrons; X-ray diffraction; Phase transformation; Synchrotron; Texture;

fLanguage

English

Publisher

ieee

Conference_Titel

Applications of Ferroelectric and Workshop on the Piezoresponse Force Microscopy (ISAF/PFM), 2013 IEEE International Symposium on the

Conference_Location

Prague

Type

conf

DOI

10.1109/ISAF.2013.6748721

Filename

6748721