• DocumentCode
    3436470
  • Title

    Factors affecting the performance of Li/SOCl2/C-TAA cells

  • Author

    Walsh, Fraser

  • Author_Institution
    ECO Energy Conversion, Somerville, MA, USA
  • fYear
    1990
  • fDate
    25-28 Jun 1990
  • Firstpage
    199
  • Lastpage
    203
  • Abstract
    Electroreduction of SOCl2 at a TAA-containing carbon-based cathode results in the formation of reaction products which may affect the electrode passivating layer. The effect of selected iminium salts as electrolytes in Li/SOCl2 cells was tested. Their use as sole electrolyte was shown to significantly reduce cell performance. Their use as electrolyte additives in Li/SOCl2/TAA-C cells was shown to be beneficial in certain cell designs, with their effect seemingly one of altering the characteristics of the passivation layer at the separator-cathode surface
  • Keywords
    cathodes; electrochemical electrodes; electrochemistry; electrolytes; lithium; primary cells; reduction (chemical); sulphur compounds; C cells; Li-SOCl2 cells; TAA-containing carbon-based cathode; electrode; electrolytes; electroreduction; iminium salts; passivating layer; separator-cathode surface; Bonding; Cathodes; Chemicals; Electrons; Equations; Glass; Iron; Particle separators; Spectroscopy; Welding;
  • fLanguage
    English
  • Publisher
    ieee
  • Conference_Titel
    Power Sources Symposium, 1990., Proceedings of the 34th International
  • Conference_Location
    Cherry Hill, NJ
  • Print_ISBN
    0-87942-604-7
  • Type

    conf

  • DOI
    10.1109/IPSS.1990.145826
  • Filename
    145826
    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=49&DC=3436470