Title :
Equipment for microwave assisted thermal cracking of hydrocarbons
Author :
Senise, José T. ; Jermolovicius, Luiz A. ; De Castro, Edmilson R. ; Nascimento, Renata B do ; Cinquini, Marina M.
Author_Institution :
Lab. de Micro-ondas, Centro Univ. do Inst. Maua de Tecnol., São Caetano do Sul, Brazil
fDate :
Oct. 29 2011-Nov. 1 2011
Abstract :
This paper exposes an application of microwaves to petroleum industry, the thermal cracking of hydrocarbons. An equipment to perform microwave assisted thermal cracking is described. This device includes a 2.45 GHz, 3 kW microwave generator and a continuous vapor phase flow reactor. The hydrocarbon feed is irradiated by microwaves over silicon carbide susceptor resulting in the hydrocarbon thermal cracking reaction. Analyses of mass spectrometry coupled with gas chromatography (GC-MS) of cracking outputs were performed and confirmed the occurrence of cracking. A naphtha feed with hydrocarbons with molecular weights within 106 and 196 produced light hydrocarbons with molecular weights within 42 and 106.
Keywords :
carbon compounds; chemical reactors; chromatography; mass spectra; microwave technology; molecular weight; oil technology; petrochemicals; pyrolysis; radiation effects; silicon compounds; GC-MS analysis; continuous vapor phase flow reactors; gas chromatography-mass spectrometry analysis; hydrocarbon feeds; microwave assisted hydrocarbon thermal cracking; microwave generators; microwave irradiation; molecular weights; naphtha feed; petroleum industry; silicon carbide susceptors; Electromagnetic heating; Hydrocarbons; Inductors; Microwave filters; cracking reactor; hydrocarbons; microwave chemistry; thermal cracking;
Conference_Titel :
Microwave & Optoelectronics Conference (IMOC), 2011 SBMO/IEEE MTT-S International
Conference_Location :
Natal
Print_ISBN :
978-1-4577-1662-1
DOI :
10.1109/IMOC.2011.6169235