DocumentCode :
3549857
Title :
Role of oxygen vacancies in VFB/Vt stability of pFET metals on HfO2
Author :
Cartier, E. ; McFeely, F.R. ; Narayanan, V. ; Jamison, P. ; Linder, B.P. ; Copel, M. ; Paruchuri, V.K. ; Basker, V.S. ; Haight, R. ; Lim, D. ; Carruthers, R. ; Shaw, T. ; Steen, M. ; Sleight, J. ; Rubino, J. ; Deligianni, H. ; Guha, S. ; Jammy, R. ; Shahi
Author_Institution :
IBM Semicond. R&D Center, Yorktown Heights, NY, USA
fYear :
2005
fDate :
14-16 June 2005
Firstpage :
230
Lastpage :
231
Abstract :
We demonstrate experimentally that the flatband/threshold voltages (VFB/Vt) of pFET metal gates are strongly dependent on the post-deposition annealing conditions of the gate stacks. By varying the temperature and the O2 partial pressure during post-deposition N2/O2 and/or forming gas annealing (FGA) with Re, Ru and Pt, the gate stack VFB can change by as much as 750 mV. However, using Re as an example, it is shown that conditions can be optimized and VFB/Vt-tuning for pFETs can be achieved for aggressively scaled stacks. It is proposed that charge transfer from oxygen vacancies to the gate electrode, possible only for high workfunction metal gates, leads to the formation of a dipole layer near the gate which can shift VFB/Vt. The results indicate that VFB/Vt control remains a formidable processing challenge with high workfunction metals on HfO2.
Keywords :
MIS structures; MISFET; annealing; hafnium compounds; oxygen; semiconductor device reliability; HfO2; VFB/Vt stability; dipole layer; flatband/threshold voltages; forming gas annealing; gate electrode; gate stack; high workfunction metal gate; oxygen vacancy; pFET metal gate; post-deposition annealing condition; Annealing; Capacitance; Channel bank filters; Electrodes; Hafnium oxide; MOS capacitors; Oxygen; Stability; Temperature; Voltage;
fLanguage :
English
Publisher :
ieee
Conference_Titel :
VLSI Technology, 2005. Digest of Technical Papers. 2005 Symposium on
Print_ISBN :
4-900784-00-1
Type :
conf
DOI :
10.1109/.2005.1469279
Filename :
1469279
Link To Document :
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