• DocumentCode
    3711466
  • Title

    The effect of Ag incorporation on the phase stability, crystallinity and band structure on the (Cu,Ag)2ZnSn(S,Se)4 kesterite solar cells

  • Author

    Shih-Yuan Wei; Chung-Hao Cai; Wei-Chih Huang; Tzu-Hsuan Yeh; Chih-Huang Lai

  • Author_Institution
    Department of Material Science and Engineering, National Tsing Hua University, Hsinchu, 30013, Taiwan
  • fYear
    2015
  • fDate
    6/1/2015 12:00:00 AM
  • Firstpage
    1
  • Lastpage
    4
  • Abstract
    The effect of Ag incorporation on the kesterite CZTSSe thin film by vacuum process has been investigated aiming for the band engineering of the kesterite solar cells. Phase stability, crystalinity, morphology and optical properties of Ag2ZnSnSe thin film were firstly reported and measured by XRD, SEM and UV-visible spectrometer in this work. We have successfully fabricated the ACZTSe thin films over a wide range of composition and the optical band gap could be controlled by the Ag/(Cu+Ag) ratio in a range from 1.06eV to 1.3 eV. Finally, the cell performance around 4% was demonstrated by the ACZTSSe devices.
  • Keywords
    "II-VI semiconductor materials","Zinc compounds","Annealing","Indexes","Photonic band gap","Boosting"
  • Publisher
    ieee
  • Conference_Titel
    Photovoltaic Specialist Conference (PVSC), 2015 IEEE 42nd
  • Type

    conf

  • DOI
    10.1109/PVSC.2015.7356188
  • Filename
    7356188