Title :
9% efficiency: CIGS on Cu substrate
Author :
Rechid, J. ; Thyen, R. ; Raitzig, A. ; Wulff, S. ; Mihhailova, M. ; Kalberlah, K. ; Kampmann, A.
Author_Institution :
CIS Solartechnik GmbH, Hamburg, Germany
Abstract :
The CIS Solartechnik is aiming at an industrial roll to roll process for the production of CIGS solar cells on metal substrates. For today we can report about a success concerning the efficiency. We are able to process ClGS solar cells on both Cu and stainless steel substrates with an efficiency of 9%. The absorber is synthesised by annealing the electrodeposited stacked metal layers of Cu, In and Ga. Se is added prior to the annealing by evaporation. The fabrication of high-efficiency CIGS absorber layers by mostly electrochemical methods is a challenge per se. The most challenging step, however, in realising cells on Cu substrates is to insert a barrier on top of the substrate which prevents the Cu from diffusion into the CIGS layer during annealing. In addition, this layer has to have good adhesion to both the CIGS layer and the Cu substrate.
Keywords :
adhesion; annealing; chemical interdiffusion; copper compounds; diffusion barriers; electrodeposition; gallium compounds; indium compounds; semiconductor thin films; solar cells; ternary semiconductors; vacuum deposition; 9 percent; ClGS solar cells; Cu; Cu substrate; Cu(InGa)Se/sub 2/-Cu; absorber; adhesion; annealing; diffusion; efficiency; electrochemical method; electrodeposited stacked metal layer; evaporation; stainless steel substrate;
Conference_Titel :
Photovoltaic Energy Conversion, 2003. Proceedings of 3rd World Conference on
Conference_Location :
Osaka, Japan
Print_ISBN :
4-9901816-0-3