Title :
Toward high performance n/p GaAs solar cells grown on low dislocation density p-type SiGe substrates
Author :
Ringel, S.A. ; Andre, C.L. ; Hudait, M.K. ; Wilt, D.M. ; Clark, Eric B. ; Pitera, A.J. ; Lee, M.L. ; Fitzgerald, E.A. ; Carroll, M. ; Erdtmann, M. ; Carlin, J.A. ; Keyes, Brian M.
Author_Institution :
Dept. of Electr. Eng., Ohio State Univ., Columbus, OH, USA
Abstract :
GaAs solar cells grown on SiGe/Si virtual substrates in the n/p configuration are of interest to develop III-V/Si cell technologies with high radiation-tolerance and to demonstrate the general applicability of SiGe/Si substrates for transfer of standard multi-junction configurations. This paper reports the first study of minority carrier electron lifetimes in p-type GaAs base materials grown on low dislocation density (1/spl times/10/sup 6/ cm/sup -2/) SiGe/Si substrates and the first study of n/p III-V cells grown on SiGe as a function of threading dislocation density. Minority carrier diffusion lengths of /spl sim/4 /spl mu/m, well in excess of a typical n/p cell base thickness, are demonstrated and correlations between diffusion length and dislocation density are made. Preliminary cell results match theoretical predictions, and n/p GaAs cell efficiencies on Si in excess of 15% have been achieved. In parallel developments for p/n cells, GaAs cell areas on SiGe have been increased from 0.36 cm/sup 2/ to 4 cm/sup 2/ with no decrease in cell performance. This indicates that thermal stress induced microcracks are not limiting cell performance on SiGe/Si substrates at this stage of development. The cumulative impact of these results indicate the growing promise of SiGe virtual substrates for achieving high performance III-V solar cells grown on Si substrates utilizing SiGe buffer layers.
Keywords :
III-V semiconductors; carrier lifetime; dislocation density; gallium arsenide; minority carriers; p-n junctions; solar cells; thermal stress cracking; GaAs-SiGe-Si; SiGe-Si; cell performance; dislocation density; microcrack; minority carrier diffusion length; minority carrier electron lifetime; p-type SiGe substrate; radiation-tolerance; solar cell; standard multi-junction configuration; thermal stress; threading dislocation density;
Conference_Titel :
Photovoltaic Energy Conversion, 2003. Proceedings of 3rd World Conference on
Conference_Location :
Osaka, Japan
Print_ISBN :
4-9901816-0-3