Title :
First hot-wire deposited triple junction silicon thin film solar cell
Author :
Schropp, R.E.I. ; Adams, J. ; Bink, A. ; Bronsveld, P.C.P. ; Francke, J. ; Franken, R.H.J. ; Goldbach, H.D. ; Gordijn, A. ; Zambrano, R. J Jimenez ; Li, H. ; Lof, R.W. ; Loffler, J. ; van der Mark, G. ; Rath, J.K. ; Rusche, M. ; Stolk, R.L. ; van Veen, M.
Author_Institution :
Debye Inst., Utrecht Univ., Netherlands
Abstract :
We present the first triple junction multibandgap cells incorporating three intrinsic absorber layers that are all deposited by hot wire CVD (Cat-CVD). The bottom and middle cell have a microcrystalline silicon (/spl mu/c-Si:H) absorber layer and the top cell has an amorphous silicon (a-Si:H) intrinsic layer. The cells are made in the configuration stainless steel/n-i-p/n-i-p/n-i-p/ITO and do not comprise a textured back reflector. We obtained a V/sub oc/ of 1.835 V, J/sub sc/ of 7.97 mA/cm/sup 2/, and a fill factor of 0.624. The open circuit voltage is appropriate for this structure, assuming a value of about 0.5 V for the two microcrystalline cells. The fill factor suggests that current matching is achieved, and the high J/sub sc/ shows that there is true spectrum splitting. The triple junction cell, with an efficiency of 9.1%, represents a considerable improvement over our previously presented HWCVD /spl mu/c-Si:H/a-Si:H tandem cells, which had an efficiency of 8.1%. No germanium has been used for this multibandgap cell. The elimination of germane and the use of HWCVD as a fast deposition technique make this triple junction cell concept very attractive for low cost, high efficiency thin film photovoltaic technology.
Keywords :
amorphous semiconductors; chemical vapour deposition; elemental semiconductors; semiconductor growth; semiconductor thin films; silicon; solar cells; 1.835 V; Si:H; amorphous silicon intrinsic layer; current matching; hot wire CVD microcrystalline-Si:H/amorphous-Si:H tandem cells; hot wire CVD triple junction silicon thin film solar cell; intrinsic absorber layers; microcrystalline cells; open circuit voltage; photovoltaic technology; spectrum splitting; stainless steel/n-i-p/n-i-p/n-i-p/ITO; textured back reflector; triple junction multibandgap solar cells;
Conference_Titel :
Photovoltaic Energy Conversion, 2003. Proceedings of 3rd World Conference on
Conference_Location :
Osaka, Japan
Print_ISBN :
4-9901816-0-3