DocumentCode
445714
Title
Preparation of enantiopure sultams by intramolecular diels-alder reaction of 1,3-cyclohexadiene-containing vinylsulfonamides
Author
Rogachev, Victor O. ; Metz, Peter
Author_Institution
Tomsk Polytech. Univ., Russia
Volume
2
fYear
2004
fDate
26 June-3 July 2004
Firstpage
76
Abstract
Enantiomerically pure δ-sultams have been prepared by intramolecular [4+2] cycloaddition of N-1-phenylethy substituted vinylsulfonamides with purely thermal activation and under high pressure. An optimized procedure for reductive debenzylation of the resultant δ-sultams is also reported.
Keywords
materials preparation; organic compounds; reduction (chemical); 1,3-cyclohexadiene-containing vinylsulfonamides; N-1-phenylethy substituted vinylsulfonamides; enantiomerically pure δ-sultams; enantiopure sultams; intramolecular cycloaddition; intramolecular diels-alder reaction; reductive debenzylation; thermal activation; Biological materials; Ceramics; Chemicals; Corrosion; Electrical resistance measurement; Gas industry; Mechanical variables measurement; Oxidation; Protection; Testing;
fLanguage
English
Publisher
ieee
Conference_Titel
Science and Technology, 2004. KORUS 2004. Proceedings. The 8th Russian-Korean International Symposium on
Print_ISBN
0-7803-8383-4
Type
conf
DOI
10.1109/KORUS.2004.1555545
Filename
1555545
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