• DocumentCode
    459070
  • Title

    Systemic Approach for Numerical Modeling and Simulation of the Impulse Response for Rapid Reaction Cu2+ - S2O32-

  • Author

    Unguresan, Mihaela Ligia ; Colosi, Tiberiu ; Surducan, Emanoil ; Surducan, Vasile

  • Author_Institution
    Dept. of Chem., Tech. Univ. of Cluj-Napoca
  • Volume
    1
  • fYear
    2006
  • fDate
    25-28 May 2006
  • Firstpage
    72
  • Lastpage
    76
  • Abstract
    The kinetics of reaction between Cu2+ and S2O3 2- and formation of an intermediate complex, CuS2O3, are investigated. The kinetics of fading away of the color of this complex has been traced spectrophotometrically using a stopped-flow apparatus. The experimental reaction order is consistent with the mechanism involving in the first step complex´s fast formation and in the second, the reaction between two complex molecules. For family of curves y = y(t, p), experimentally rise up, y is the light intensity and it is considered as dependent on time t [ms] and concentration p[mol/l]. We are following the significant stages of identification - numerical modeling and simulation, in a usual systemic variant. The results run on the computer are being compared and interpreted in report to the experimental measurements
  • Keywords
    copper; numerical analysis; reaction kinetics; reduction (chemical); sulphur compounds; Cu2+; S2O3 2-; Taylor series; exponential functions; impulse response; numerical integration; numerical modeling; numerical simulation; partial differential equations; rapid redox reaction; reaction kinetics; state variables; stopped-flow apparatus; successive reaction; Analytical models; Automation; Chemicals; Computational modeling; Copper; Fading; Kinetic theory; Numerical models; Numerical simulation; Partial differential equations; Taylor series; exponential functions; numerical integration; partial differential equations; rapid redox reaction; state variables; successive reaction;
  • fLanguage
    English
  • Publisher
    ieee
  • Conference_Titel
    Automation, Quality and Testing, Robotics, 2006 IEEE International Conference on
  • Conference_Location
    Cluj-Napoca
  • Print_ISBN
    1-4244-0360-X
  • Electronic_ISBN
    1-4244-0361-8
  • Type

    conf

  • DOI
    10.1109/AQTR.2006.254500
  • Filename
    4022822