Insulating properties and charge characteristics of natural ester fluid modified by TiO2 semiconductive nanoparticles

In order to improve dielectric performance of natural esters, TiO₂ semiconductive nanoparticles were added to obtain an ester-based nanofluid. AC, lightning impulse voltage and partial discharge tests were applied to the natural ester and the ester-based nanofluid to check their dielectric performances. It was found that TiO₂ nanoparticles can not only enhance AC breakdown voltage of the ester based nanofluid by a factor of 1.3 but also improve the partial discharge properties of the ester based nanofluid compared to that of the natural ester. Pulse electroacoustic (PEA) and thermally stimulated current (TSC) techniques were applied to investigate charge transport and trap characteristic in natural ester and ester-based nanofluid. It reveals that TiO₂ nanoparticles can accelerate the charge dissipation rate and uniform the electric field and increase the shallow trap density in the ester-based nanofluid. It is proposed that electron trapping and de-trapping processes in the shallow traps could be one of the main charge transport processes in the ester based nanofluid.