Title :
Simultaneous Spectrophotometric Determination of Copper, Zinc, Nickel and Cobalt in Water Using Principal Component Regression Coupled with Wavelet Transform
Author :
Ma, Xiaoguo ; Huang, Dahai
Author_Institution :
Fac. of Environ. Sci. & Eng., Guangdong Univ. of Technol., Guangzhou, China
Abstract :
This paper describes the simultaneous spectrophotometric determination of copper, zinc, nickel and cobalt in water with 5-Br-PADAP. The absorbance spectra obtained were processed with wavelet transform (WT) for removal of noise from the spectra. In order to eliminate spectral interferences, calculation of the metal concentrations in mixtures was performed using principal component regression (PCR). The results showed that the combination of MT and PCR allowed more accurate and precious spectrophotometric determination of these ions than traditional PCR approach.
Keywords :
cobalt; copper; hydrological techniques; nickel; principal component analysis; regression analysis; spectrophotometry; water quality; wavelet transforms; zinc; Co; Cu; Ni; Zn; absorbance spectra; principal component regression; spectral interference; spectrophotometry; water; wavelet transform; Cobalt; Continuous wavelet transforms; Copper; Matrix decomposition; Nickel; Paper technology; Signal analysis; Wavelet analysis; Wavelet transforms; Zinc; Cobalt; Copper; Nickel; Principal component regression; Spectrophotometry; Wavelet transform; Zinc;
Conference_Titel :
Energy and Environment Technology, 2009. ICEET '09. International Conference on
Conference_Location :
Guilin, Guangxi
Print_ISBN :
978-0-7695-3819-8
DOI :
10.1109/ICEET.2009.418