Single Crystal Growth, Structure Determination and Third-Order Nonlinear Optical Property Study of a Nickel Complex Constructed by Imidazole Ligand

Author

Ting Bin Li ; Ya Li Hu ; Ren, Quan ; Xu, Dong

Author_Institution

Dept. of Mater. Sci. & Technol., Taishan Univ., Taian, China

fYear

2010

fDate

19-21 June 2010

Firstpage

1

Lastpage

3

Abstract

A nickel complex constructed by the ligand: imidazole has been synthesized, using solvent evaporation method its single crystal was successfully obtained. Its structure has been determined by means of X-ray single crystal diffraction. Its third-order nonlinear optical property has been studied using Z-scan technique with 20 picosecond (ps) pulses at wavelength 1064 nm. Its molecular second hyperpolarizability γ was determined to be 2.295×10^-57 Om⁴/V³.

Keywords

X-ray diffraction; absorption coefficients; crystal growth from solution; crystal structure; evaporation; materials preparation; nickel compounds; nonlinear optics; optical materials; organic compounds; polarisability; X-ray single crystal diffraction; Z-scan technique; crystal growth; imidazole ligand; molecular second hyperpolarizability; nickel complex; solvent evaporation method; structure determination; third-order nonlinear optical property; time 20 ps; wavelength 1064 nm; Extraterrestrial measurements; Hydrogen; Nickel; Nonlinear optics; Optical materials; Optical modulation; Optical polymers; Performance evaluation; Solvents; Ultrafast optics;

fLanguage

English

Publisher

ieee

Conference_Titel

Photonics and Optoelectronic (SOPO), 2010 Symposium on

Conference_Location

Chengdu

Print_ISBN

978-1-4244-4963-7

Electronic_ISBN

978-1-4244-4964-4

Type

conf

DOI

10.1109/SOPO.2010.5504295

Filename

5504295